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VYŠVAŘIL, M. DASTYCH, D. TARABA, J. NEČAS, M.
Originální název
Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group
Typ
článek v časopise ve Web of Science, Jimp
Jazyk
angličtina
Originální abstrakt
A series of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group were synthesized and characterized by 1H, 13C{1H} and 31P NMR spectroscopy, IR and MS. PhmPCln (m = 3; n, n = 3, 2, 1) reacted with 3,3,4,4-tetramethylsuccinimide (TH) and potassium 3,3,4,4-tetramethylsuccinimidate to give corresponding PhmPTn. Molecular structures of products were established by single-crystal X-ray diffraction experiments. Attempts to prepare new imidophosphoranes by reactions of 1 with PhmPCln (m = 5; n, n = 4, 3, 2) resulted in phosphine oxides. In these reactions the phosphoryl group was formed and we characterized a by-product of this type of reaction.
Klíčová slova
succinimide, phosphanes, phosphine oxides, substitution, phosphoryl group
Autoři
VYŠVAŘIL, M.; DASTYCH, D.; TARABA, J.; NEČAS, M.
Vydáno
10. 11. 2009
Nakladatel
Elsevier
ISSN
0020-1693
Periodikum
INORGANICA CHIMICA ACTA
Ročník
2009
Číslo
362
Stát
Švýcarská konfederace
Strany od
4899
Strany do
4905
Strany počet
7
BibTex
@article{BUT48955, author="VYŠVAŘIL, M. and DASTYCH, D. and TARABA, J. and NEČAS, M.", title="Synthesis and characterization of new imidophosphanes and phosphine oxides containing 3,3,4,4-tetramethylsuccinimidyl group", journal="INORGANICA CHIMICA ACTA", year="2009", volume="2009", number="362", pages="4899--4905", issn="0020-1693" }