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ZÍTKA, O. KRYŠTOFOVÁ, O. ŠOBROVÁ, P. ADAM, V. ZEHNÁLEK, J. BEKLOVÁ, M. KIZEK, R.
Original Title
Phytochelatin synthase activity as a marker of metal pollution
Type
journal article in Web of Science
Language
English
Original Abstract
The synthesis of phytochelatins is catalyzed by gamma-Glu-Cys dipeptidyl transpeptidase called phytochelatin synthase (PCS). Aim of this study was to suggest a new tool for determination of phytochelatin synthase activity in the tobacco BY-2 cells treated with different concentrations of the Cd(II). After the optimization steps, an experiment on BY-2 cells exposed to different concentrations of Cd(NO3)2 for 3 days was performed. At the end of the experiment, cells were harvested and homogenized. Reduced glutathione and cadmium (II) ions were added to the cell suspension supernatant. These mixtures were incubated at 35 C for 30 min and analysed using high performance liquid chromatography coupled with electrochemical detector (HPLC-ED). The results revealed that PCS activity rises markedly with increasing concentration of cadmium (II) ions. The lowest concentration of the toxic metal ions caused almost three fold increase in PCS activity as compared to control samples. The activity of PCS (270 fkat) in treated cells was more than seven times higher in comparison to control ones. Km for PCS was estimated as 2.3 mM.
Keywords
Phytochelatin synthase activity, Cadmium, Glutathione, High performance liquid chromatography with electrochemical detection, Tobacco BY-2 cell suspension
Authors
ZÍTKA, O.; KRYŠTOFOVÁ, O.; ŠOBROVÁ, P.; ADAM, V.; ZEHNÁLEK, J.; BEKLOVÁ, M.; KIZEK, R.
RIV year
2011
Released
2. 6. 2011
Publisher
Elsevier
ISBN
0304-3894
Periodical
Journal of Hazardous Materials
Year of study
2011 (192)
Number
1
State
Kingdom of the Netherlands
Pages from
794
Pages to
800
Pages count
7
BibTex
@article{BUT75096, author="Ondřej {Zítka} and Olga {Kryštofová} and Pavlína {Adam} and Vojtěch {Adam} and Josef {Zehnálek} and Miroslava {Beklová} and René {Kizek}", title="Phytochelatin synthase activity as a marker of metal pollution", journal="Journal of Hazardous Materials", year="2011", volume="2011 (192)", number="1", pages="794--800", doi="10.1016/j.jhazmat.2011.05.088", issn="0304-3894" }