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BÁBÍK, A. MISTRÍK, J. ZEMEK, J. ČECH, V.
Original Title
Self-assembled monolayers of vinyltriethoxysilane and vinyltrichlorosilane deposited on silicon dioxide surfaces
Type
journal article - other
Language
English
Original Abstract
This study was aimed at deposition of self-assembled monolayers (SAMs) using vinyltriethoxysilane (VTES) and vinyltrichlorosilane (VTCS) molecules chemisorbed on silicon dioxide surfaces. The kinetics of SAM formation on planar glass substrates and silicon wafers was characterized by contact angle measurements. The surface free energy and its dispersion and polar components enabled to estimate the time of immersion required to deposit compact SAMs. Adsorption of organosilane molecules as a function of immersion time was characterized by X-ray photoelectron spectroscopy. The SAM thickness was evaluated by spectroscopic ellipsometry. Surface topography of deposited layers was investigated by atomic force microscopy (AFM). The VTCS/glass combination exhibited the fastest kinetics but the deposit was not uniform and included local agglomerates. The hydrophobic vinyl groups at deposit surface resulted in a surface free energy of 32 mJ m-2.
Keywords
Self-assembled monolayers, organosilanes, contact angle, surface free energy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS)
Authors
BÁBÍK, A.; MISTRÍK, J.; ZEMEK, J.; ČECH, V.
RIV year
2012
Released
17. 12. 2012
ISBN
0169-4243
Periodical
Journal of Adhesion Science and Technology
Year of study
26
Number
22
State
Kingdom of the Netherlands
Pages from
2543
Pages to
2554
Pages count
12
BibTex
@article{BUT97132, author="Adam {Bábík} and Jan {Mistrík} and Josef {Zemek} and Vladimír {Čech}", title="Self-assembled monolayers of vinyltriethoxysilane and vinyltrichlorosilane deposited on silicon dioxide surfaces", journal="Journal of Adhesion Science and Technology", year="2012", volume="26", number="22", pages="2543--2554", issn="0169-4243" }