Course detail
Binders II
FAST-BJ16Acad. year: 2013/2014
Concise principles of thermodynamics, the first and second law of thermodynamics, heat of formation, chemical equilibrium, Guldberg-Waag law, system out-of-equilibrium, reaction isotherm, State behaviour of liquids, skin effects, cohesive pressure, transport phenomena in liquids, Phase equilibria, one component system, Gibbs law, two components system. Heterogeneous one-, two-, and more components system, solubility of gases in liquids. Solid phase-gas system, solid phase - liquid phase, ternary systems. Electrochemistry, Faraday’s laws, molar conductivity of weak and strong electrolytes, Wheatstone bridge, dissociation and hydrolysis, ionic product of water, galvanic cells. Disperse systems, classification, basic physical properties, coagulation, zeta potential. Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd and higher orders, catalysts.
The structure of silicates, Pauling’s principles, basic structural arrangement. Clay minerals, structural arrangement, classification, water bound in clay minerals. Structure and properties of silicate melts, crystallization of melts, glass structures. Heterogeneous equilibria in silicate systems, solid state reactions.
Lectures are complemented by computational and laboratory exercises.
Language of instruction
Number of ECTS credits
Mode of study
Guarantor
Department
Learning outcomes of the course unit
The student would manage the goal of the subject by acquiring knowledge on the basics of physical chemistry from the field of physical states of substances, thermodynamics, reaction kinetics, processes on the interface boundaries, sorptive effects and basic exposure of the disperse systems, further by knowledge on silicate chemistry from the field of silicate structure, melt and glass theory, theory of reaction in the solid phase.
Prerequisites
Co-requisites
Planned learning activities and teaching methods
Assesment methods and criteria linked to learning outcomes
The final exam consists of a written and oral part.
Course curriculum
2.State behaviour of liquids, surface effects, cohesion pressure, transport processes in liquids.
3.Phase equilibria, one component system, Gibbs Law of phases, system with two components.
4.Heterogeneous one-, two- and more-components systems, solubility of gases in liquids.
5.The systems: solid phase-gas, solid phase-liquid phase, ternary systems.
6.Electrochemistry, Faradays Laws, molar conductivity of weak and strong electrolytes, the Wheatstone´s bridge, dissociation and hydrolysis, ionic product of water, galvanic elements.
7.Disperse systems, division, basic physical properties, coagulation, zeta-potential.
8.Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd, and higher orders, catalysts.
9.Structure of silicates, Pauling´s principles, basic structural arrangement.
10.Clay minerals, structural arrangement.
11.Classification of clay minerals, water bond in clay minerals.
12.Structure and the properties of silicate melt.
13.Melt crystallisation, the structure of glass.Heterogeneous equilibria in silicate systems, reactions in solid state.
Work placements
Aims
Specification of controlled education, way of implementation and compensation for absences
Recommended optional programme components
Prerequisites and corequisites
Basic literature
Recommended reading
EITEL W.: Silicite science. Academie Press N. Y. USA, 1964. (EN)
Kingery, W.D.: Introduction to Ceramics. New York - J. Wiley, 1962. (EN)
Lach,V.,Daňková,M.: Mikrostruktura stavebních látek. VUT v Brně, 1991. ISBN 80-214-0309-8. (CS)
Walter J. Moore: Physical chemistry. Englewood Cliffs, N. J. USA, 1994.
Classification of course in study plans
Type of course unit
Lecture
Teacher / Lecturer
Syllabus
2.State behaviour of liquids, surface effects, cohesion pressure, transport processes in liquids.
3.Phase equilibria, one component system, Gibbs Law of phases, system with two components.
4.Heterogeneous one-, two- and more-components systems, solubility of gases in liquids.
5.The systems: solid phase-gas, solid phase-liquid phase, ternary systems.
6.Electrochemistry, Faradays Laws, molar conductivity of weak and strong electrolytes, the Wheatstone´s bridge, dissociation and hydrolysis, ionic product of water, galvanic elements.
7.Disperse systems, division, basic physical properties, coagulation, zeta-potential.
8.Reaction kinetics, order and molecularity of reaction, reactions of 1st, 2nd, and higher orders, catalysts.
9.Structure of silicates, Pauling´s principles, basic structural arrangement.
10.Clay minerals, structural arrangement. Classification of clay minerals, water bond in clay minerals.
11.Structure and the properties of silicate melt. Melt crystallisation, the structure of glass.Heterogeneous equilibria in silicate systems, reactions in solid state.
Exercise
Teacher / Lecturer
Syllabus
2. Transport processes in liquids
3. Phase equilibria - Calculations of, one component system and two components system
4. Molar conductivity of weak and strong electrolytes
5. Reaction kinetics - Calculations of reactions of 1st, 2nd, and higher orders
6. Heterogeneous one-, two- and more-components systems
7. Disperse systems
8. Zeta-potential
9. XRD analysis of silicates
10. Excursion
11. Credit