Detail publikace

Raman antenna effect from exciton–phonon coupling in organic semiconducting nanobelts

WANG, M. GONG, Y. ALZINA, F. SVOBODA, O. BALLESTEROS, B. TORRES, C. XIAO, S. HE, J. ZHANG, Z.

Originální název

Raman antenna effect from exciton–phonon coupling in organic semiconducting nanobelts

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

The highly anisotropic interactions in organic semiconductors together with the soft character of organic materials lead to strong coupling between nuclear vibrations and exciton dynamics, which potentially results in anomalous electrical, optical and optoelectrical properties. Here, we report on the Raman antenna effect from organic semiconducting nanobelts 6,13-dichloropentacene (DCP), resulting from the coupling of molecular excitons and intramolecular phonons. The highly ordered crystalline structure in DCP nanobelts enables the precise polarization-resolved spectroscopic measurement. The angle-dependent Raman spectroscopy under resonant excitation shows that all Raman modes from the skeletal vibrations of DCP molecule act like a nearly perfect dipole antenna IRaman ∝ cos4(θ − 90), with almost zero (maximum) Raman scattering parallel (perpendicular) to the nanobelt's long-axis. The Raman antenna effect in DCP nanobelt is originated from the coupling between molecular skeletal vibrations and intramolecular exciton and the confinement of intermolecular excitons. It dramatically enhances the Raman polarization ratio (ρ = I‖/I⊥ > 25) and amplifies the anisotropy of the angle-dependent Raman scattering (κRaman = Imax/Imin > 12) of DCP nanobelts. These findings have crucial implications for fundamental understanding on the exciton–phonon coupling and its effects on the optical properties of organic semiconductors.

Klíčová slova

FIELD-EFFECT TRANSISTORS; CHARGE-TRANSPORT; SINGLE-CRYSTALS; SPECTROSCOPY; PENTACENE; 6,13-DICHLOROPENTACENE; FABRICATION; NANOWIRES; POLYMER; DEVICES

Autoři

WANG, M.; GONG, Y.; ALZINA, F.; SVOBODA, O.; BALLESTEROS, B.; TORRES, C.; XIAO, S.; HE, J.; ZHANG, Z.

Vydáno

27. 11. 2017

Nakladatel

ROYAL SOC CHEMISTRY

Místo

THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

ISSN

2040-3364

Periodikum

NANOSCALE

Ročník

9

Číslo

48

Stát

Spojené království Velké Británie a Severního Irska

Strany od

19328

Strany do

19336

Strany počet

9

URL

http://dx.doi.org/10.1039/C7NR07212K

BibTex

@article{BUT143260,
  author="Mao {Wang} and Yi {Gong} and Francesc {Alzina} and Ondřej {Svoboda} and Belén {Ballesteros} and Clivia Marfa Sotomayor {Torres} and Senbo {Xiao} and Jianying {He} and Zhiliang {Zhang}",
  title="Raman antenna effect from exciton–phonon coupling in organic semiconducting nanobelts",
  journal="NANOSCALE",
  year="2017",
  volume="9",
  number="48",
  pages="19328--19336",
  doi="10.1039/C7NR07212K",
  issn="2040-3364",
  url="http://dx.doi.org/10.1039/C7NR07212K"
}