Detail publikačního výsledku

Redox and optically active carbohelicene layers prepared by potentiodynamic polymerization

HRBÁČ, J.; PAVELKA, V.; CRASSOUS, J.; ŽÁDNÝ, J.; FEKETE, L.; POKORNÝ, J.; VANÝSEK, P.; STORCH, J.; VACEK, J.

Originální název

Redox and optically active carbohelicene layers prepared by potentiodynamic polymerization

Anglický název

Redox and optically active carbohelicene layers prepared by potentiodynamic polymerization

Druh

Článek WoS

Originální abstrakt

This short paper describes the preparation of thin layers based on carbohelicenes, which are inherently chiral polyaromatics existing in the enantiomeric forms P and M. Specifically, [5]-, [6]- and [7]helicene were subjected to redox cycling between -1.5 and 1.5 V vs. ferrocene/ferrocenium at a scan rate of 10 V/s. This way, enantiopure layers exhibiting redox activity were formed on the surfaces of the glassy carbon and ITO electrodes under anoxic and non-aqueous conditions. The properties of the prepared polymer layers were investigated using electrochemistry with Fe/Ru redox probes, circular dischroism, AFM, impedance measurement and Raman spectroscopy. With [6]helicene, the suggested electropolymerization procedure thus represents a proof-of-concept for the preparation of chiral carbonaceous surfaces.

Anglický abstrakt

This short paper describes the preparation of thin layers based on carbohelicenes, which are inherently chiral polyaromatics existing in the enantiomeric forms P and M. Specifically, [5]-, [6]- and [7]helicene were subjected to redox cycling between -1.5 and 1.5 V vs. ferrocene/ferrocenium at a scan rate of 10 V/s. This way, enantiopure layers exhibiting redox activity were formed on the surfaces of the glassy carbon and ITO electrodes under anoxic and non-aqueous conditions. The properties of the prepared polymer layers were investigated using electrochemistry with Fe/Ru redox probes, circular dischroism, AFM, impedance measurement and Raman spectroscopy. With [6]helicene, the suggested electropolymerization procedure thus represents a proof-of-concept for the preparation of chiral carbonaceous surfaces.

Klíčová slova

Carbohelicene; Hexahelicene; Voltammetry; Enantiopure; Redox active; Chiral carbon

Klíčová slova v angličtině

Carbohelicene; Hexahelicene; Voltammetry; Enantiopure; Redox active; Chiral carbon

Autoři

HRBÁČ, J.; PAVELKA, V.; CRASSOUS, J.; ŽÁDNÝ, J.; FEKETE, L.; POKORNÝ, J.; VANÝSEK, P.; STORCH, J.; VACEK, J.

Rok RIV

2021

Vydáno

19.02.2020

Nakladatel

Elsevier

Místo

NEW YORK

ISSN

1388-2481

Periodikum

Electrochemistry Communications

Svazek

113

Číslo

4

Stát

Spojené státy americké

Strany od

1

Strany do

5

Strany počet

5

URL

https://www.sciencedirect.com/science/article/pii/S1388248120300400

Plný text v Digitální knihovně

http://hdl.handle.net/11012/187006

BibTex

@article{BUT162535,
  author="Jan {Hrbáč} and Vit {Pavelka} and Jeanne {Crassous} and Jaroslav {Žádný} and Ladislav {Fekete} and Jan {Pokorný} and Petr {Vanýsek} and Jan {Storch} and Jan {Vacek}",
  title="Redox and optically active carbohelicene layers prepared by potentiodynamic polymerization",
  journal="Electrochemistry Communications",
  year="2020",
  volume="113",
  number="4",
  pages="1--5",
  doi="10.1016/j.elecom.2020.106689",
  issn="1388-2481",
  url="https://www.sciencedirect.com/science/article/pii/S1388248120300400"
}

Dokumenty

2020 Electrochemistry Communications 113 (2020) 106689