Detail publikace

Reconstructed Bismuth-Based Metal-Organic Framework Nanofibers for Selective CO2-to-Formate Conversion: Morphology Engineering

YING, Y. KHEZRI, B. KOSINA, J. PUMERA, M.

Originální název

Reconstructed Bismuth-Based Metal-Organic Framework Nanofibers for Selective CO2-to-Formate Conversion: Morphology Engineering

Typ

článek v časopise ve Web of Science, Jimp

Jazyk

angličtina

Originální abstrakt

Electrochemical reduction of carbon dioxide (ERCO2) is an attractive and sustainable approach to close the carbon loop. Formic acid is a high-value and readily collectible liquid product. However, the current reaction selectivity remains unsatisfactory. In this study, the bismuth-containing metal-organic framework CAU-17, with morphological variants of hexagonal prisms (CAU-17-hp) and nanofibers (CAU-17-fiber), is prepared at room temperature through a wet-chemical approach and employed as the electrocatalyst for highly selective CO2-to-formate conversion. An H3BTC-mediated morphology reconstruction is systematically investigated and further used to build a CAU-17-fiber hierarchical structure. The as-prepared CAU-17-fiber_400 electrodes give the best electrocatalytic performance in selective and efficient formate production with FEHCOO- of 96.4 % and j(COOH-) of 20.4 mA cm(-2) at -0.9 V-RHE. This work provides a new mild approach for synthesis and morphology engineering of CAU-17 and demonstrates the efficacy of morphology engineering in regulating the accessible surface area and promoting the activity of MOF-based materials for ERCO2.

Klíčová slova

carbon dioxide; electrocatalysis; formic acid; metal-organic frameworks; morphology engineering

Autoři

YING, Y.; KHEZRI, B.; KOSINA, J.; PUMERA, M.

Vydáno

23. 8. 2021

Nakladatel

WILEY-V C H VERLAG GMBH

Místo

WEINHEIM

ISSN

1864-564X

Periodikum

ChemSusChem

Ročník

14

Číslo

16

Stát

Spolková republika Německo

Strany od

3402

Strany do

3412

Strany počet

11

URL

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202101122

BibTex

@article{BUT172568,
  author="Yulong {Ying} and Bahareh {Khezri} and Jiří {Kosina} and Martin {Pumera}",
  title="Reconstructed Bismuth-Based Metal-Organic Framework Nanofibers for Selective CO2-to-Formate Conversion: Morphology Engineering",
  journal="ChemSusChem",
  year="2021",
  volume="14",
  number="16",
  pages="3402--3412",
  doi="10.1002/cssc.202101122",
  issn="1864-564X",
  url="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202101122"
}