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Original title in Czech: Chemie, technologie a vlastnosti materiálůFCHAbbreviation: DPCO_CHMAcad. year: 2011/2012
Programme: Chemistry, Technology and Properties of Materials
Length of Study: 3 years
Accredited from: 10.3.2004Accredited until: 31.7.2013
Guarantor
prof. Ing. Jaromír Havlica, DrSc.
Issued topics of Doctoral Study Program
Tutor: Havlica Jaromír, prof. Ing., DrSc.
The aim of the work is the experimental and theoretical study of properties of molecular semiconductors suitable for optical and electrical applications. The applicant will deal with characterization of physical and chemical properties of studied materials, such as generation and transport of charge carriers, conductivity and photoconductivity, optical absorption, photo- and electroluminescence. The effort will be made to reach reproducibility in preparation of molecular devices and propose the technology for their utilization in organic electronic. The work is a part of large-scale research project funded by EU.
Tutor: Weiter Martin, prof. Ing., Ph.D.
Controlled deposition of the functionally nanostructured thin films by low-temperature (nonisothermic) plasma is a new technological step for creative design and application of complex film structures in smart materials. The thesis is aimed at synthesis and characterization of anisotropic films of continuously or quasi-continuously varying physicochemical properties that are worthwhile as compatible interlayers between materials of distinct physical and chemical properties. Such anisotropic films have high application potential for passivation of organic devices, as dielectric barriers in semiconductor devices, as tribological coatings in aeronautical applications, or as functional interlayers in hybrid materials.
Tutor: Čech Vladimír, prof. RNDr., Ph.D.
Hydrogenated amorphous carbon and its alloys will be prepared in a form of thin film using monomer vapor or a mixture in selected gases by plasma-enhanced chemical vapor deposition (PECVD). Deposited films will be characterized comprehensively by microscopic and spectroscopic techniques to evaluate their physical and chemical properties.
Multifunctional gas detectors
Tutor: Nešpůrek Stanislav, prof. RNDr., DrSc.
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Tutor: Schauer Petr, RNDr., CSc.
Amorphous materials a-C:H, a-SiC:H a a-SiOC:H in a form of thin film will be studied using spectroscopic ellipsometry. The study is aimed at optical properties of single layers and functional multilayers.
Tutor: Zmeškal Oldřich, prof. Ing., CSc.
The topic includes study of optical and electrical properties of biopolymers and other biomaterials. The research will be targeted to the characterization of the possibilities of their application in advanced optoelectronic devices such as sensors. Humic acids and their salts can serve as an example. They play a key role in the soil. With respect to their partly aromatic structure they generate a free radicals after irradiation by UV and VIS light. Other biomaterials and their composites will be studied, the properties will be modified also by nanoparticles.
Plasma polymer films (interlayers) will be used to surface modify carbon fibers intended as reinforcements for polymer composites. An influence of physical and chemical properties of the deposited interlayer on composite performance will be investigated.
The Ph.D. thesis deals with the study of possibilities of analysis and mainly treatment of water quality within processes where the hydration of Portland cement takes place, such as production of fiber-cement composites, concrete prefabricated elements etc. The water quality treatment is focused on reduction of content of selected components in waste-water from such a production units or its multiple utilization within Portland cement hydration with a view to maintain the quality of cement products.